Enhancing the current density of electrodeposited ZnO-Cu 2O solar cells by engineering their heterointerfaces

• Published in: Journal of Materials Chemistry
• Main Author: Zoolfakar A.S.; Rani R.A.; Morfa A.J.; Balendhran S.; O'Mullane A.P.; Zhuiykov S.; Kalantar-Zadeh K.
• Format: Article
• Language: English
• Published: 2012
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84867030018&doi=10.1039%2fc2jm35682a&partnerID=40&md5=75971517f0cd5383e7566ed8241496fb

Using ZnO seed layers, an efficient approach for enhancing the heterointerface quality of electrodeposited ZnO-Cu 2O solar cells is devised. We introduce a sputtered ZnO seed layer followed by the sequential electrodeposition of ZnO and Cu 2O films. The seed layer is employed to control the growth and crystallinity and to augment the surface area of the electrodeposited ZnO films, thereby tuning the quality of the ZnO-Cu 2O heterointerface. Additionally, the seed layer also assists in forming high quality ZnO films, with no pin-holes, in a high pH electrolyte solution. X-ray electron diffraction patterns, scanning electron and atomic force microscopy images, as well as photovoltaic measurements, clearly demonstrate that the incorporation of certain seed layers results in the alteration of the heterointerface quality, a change in the heterojunction area and the crystallinity of the films near the junction, which influence the current density of photovoltaic devices. © 2012 The Royal Society of Chemistry.