Wear characterization of nano-hydroxyapatite with addition of titanium (HA-Ti)

• Published in: IOP Conference Series: Materials Science and Engineering
• Main Author: Rosmamuhamadani R.; Arawi A.Z.O.; Talari M.K.; Mahat M.M.; Bonnia N.N.; Sabrina; Yahaya M.; Sulaiman S.; Ismail M.I.S.
• Format: Conference paper
• Language: English
• Published: Institute of Physics Publishing 2018
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85047798003&doi=10.1088%2f1757-899X%2f348%2f1%2f012001&partnerID=40&md5=304b2229f287aeac278ab6f6f34cf3c9

Hydroxyapatite (Ca10 (PO4)6(OH)2, HA), is an attractive material of an inorganic compound whose chemical composition and crystallographic structures are similar to the composition of the bone. A natural source such as egg shells is composed of 94 wt. % of calcium carbonate (CaCO3), which can be calcined as calcium oxide (CaO) by the calcinations process. The efficient temperature to produce CaO is 900 °C for 2 hours. The synthesis of nano-HA was done by the mixing the diammonium phosphate (DAP) and calcium hydroxide (Ca(OH)2) and subjected into a microwave for 30 minutes at 1100 W irradiation power. Ball milling process was used for 30 minutes to mix the nano-HA with different compositions of titanium. These were pressed to form pallets by hand hydraulic pump (force=2300 psi). The pallets then were sintered at 1200 °C with the heating rate of 3 °C/min for 2 hours. The pallets were tested by several mechanical testing including hardness, compression strength and wear. From the results, HA-25wt. %Ti composite gave the highest hardness, compression and coefficient of friction for wear test values which were 89.6 Hv, 82.5MPa and 0.76μ respectively. It showed that by adding Ti to nano-HA, the mechanical properties of nano-HA could be enhanced. The microstructure analyses by optical micrograph showed that nano-HA-Ti particles displayed shape likes needle morphology. The particles showed the high tendency to form the agglomerations. © Published under licence by IOP Publishing Ltd.