Preparation of conductive cellulose paper through electrochemical exfoliation of graphite: The role of anionic surfactant ionic liquids as exfoliating and stabilizing agents

A facile electrochemical exfoliation method was established to efficiently prepare conductive paper containing reduced graphene oxide (RGO) with the help of single chain anionic surfactant ionic liquids (SAILs). The surfactant ionic liquids are synthesized from conventional organic surfactant anions...

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Bibliographic Details
Published in:Carbohydrate Polymers
Main Author: Mohamed A.; Ardyani T.; Bakar S.A.; Sagisaka M.; Umetsu Y.; Hussin M.R.M.; Ahmad M.K.; Mamat M.H.; King S.; Czajka A.; Hill C.; Eastoe J.
Format: Article
Language:English
Published: Elsevier Ltd 2018
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85051636294&doi=10.1016%2fj.carbpol.2018.08.040&partnerID=40&md5=5ad5bd96d79fed318abf645d8471f2fc
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Summary:A facile electrochemical exfoliation method was established to efficiently prepare conductive paper containing reduced graphene oxide (RGO) with the help of single chain anionic surfactant ionic liquids (SAILs). The surfactant ionic liquids are synthesized from conventional organic surfactant anions and a 1-butyl-3-methyl-imidazolium cation. For the first time the combination of SAILs and cellulose was used to directly exfoliate graphite. The ionic liquid 1-butyl-3-methyl-imidazolium dodecylbenzenesulfonate (BMIM-DBS) was shown to have notable affinity for graphene, demonstrating improved electrical properties of the conductive cellulose paper. The presence of BMIM-DBS in the system promotes five orders of magnitude enhancement of the paper electrical conductivity (2.71 × 10−5 S cm−1) compared to the native cellulose (1.97 × 10−10 S cm−1). A thorough investigation using electron microscopy and Raman spectroscopy highlights the presence of uniform graphene incorporated inside the matrices. Studies into aqueous aggregation behavior using small-angle neutron scattering (SANS) point to the ability of this compound to act as a bridge between graphene and cellulose, and is responsible for the enhanced exfoliation level and stabilization of the resulting dispersion. The simple and feasible process for producing conductive paper described here is attractive for the possibility of scaling-up this technique for mass production of conductive composites containing graphene or other layered materials. © 2018 Elsevier Ltd
ISSN:1448617
DOI:10.1016/j.carbpol.2018.08.040