Characteristic, thermochemical behaviors and kinetic of demineralized and torrefied empty fruit bunches (EFB)

• Published in: Advances in Science, Technology and Engineering Systems
• Main Author: Kasim N.N.; Ismail K.; Mohamed A.R.; Ishak M.A.M.; Ahmad R.; Ismail W.I.N.W.
• Format: Article
• Language: English
• Published: ASTES Publishers 2018
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85061777099&doi=10.25046%2faj030542&partnerID=40&md5=cdbeaa7481a9f2eb0eca769312a9131d

A sequential pre-treatment of demineralization and torrefaction, was carried out on palm empty fruit bunches (EFB). EFB and demineralized EFB (DEFB) were torrefied in a vertical tubular reactor in the temperature range of 200 to 280 °C for 30 mins under nitrogen (flow rate:100 mL/min. The pretreated samples were characterized using proximate and ultimate analyses, fuel properties, and Fourier-transform infrared (FTIR) spectroscopy techniques. The thermal and kinetic study on the torrefied samples were carried out using thermogravimetric analysis. The results showed that sequential pretreatment enhances the properties of solid EFB by increasing the carbon content and reducing the oxygen content with increasing the calorific value. Fuel properties of torrefied samples showed the mass and energy yield decreased, with an increase in energy density. In addition, the FTIR spectra showed the decomposition of hemicellulose occurring for torrefied samples as evidenced by the disappearance of the vibrational features belonging to hydroxyl and carbonyl groups. The kinetic study carried out using Coats-Redfern method on torrefied samples suggested that the activation energy can be transferred by the sequential pre-treatment, indicating that the abundant energy it has can be converted into bio oil of high quality. Apparently, torrefied samples bear high potential to be used as biofuel feedstock when exposed to further thermal decomposition and pyrolysis processes. © Advances in Science, Technology and Engineering Systems. All rights reserved.