Reductive transformation of tetrachloroethene catalyzed by sulfide-cobalamin in nano-mackinawite suspension
In this study, we demonstrated the reductive substitution of aquo-cobalamin(III) (Cbl(III)-H2O) by sulfide-cobalamin(III) (Cbl(III)-S2-) in the presence of S2-. Cbl(III)-H2O was transformed to Cbl(III)-S2- via ligand substitution of H2O by S2- at its axial position, due to the weakness of the bond s...