Blended mangosteen/pomegranate peels as a precursor for porous carbon material via microwave assisted-potassium carbonate activation: Box-Benken design optimization for fuchsin basic and methylene violet dyes removal

• 发表在: DIAMOND AND RELATED MATERIALS
• Main Authors: Irwan, Siti Aishah; Jawad, Ali H.; Deris, Raja Razuan Raja; Musa, Salis A.; Wu, Ruihong; Alothman, Zeid A.
• 格式: 文件
• 语言: English
• 出版: ELSEVIER SCIENCE SA 2025
• 主题: Materials Science; Physics
• 在线阅读: https://www-webofscience-com.uitm.idm.oclc.org/wos/woscc/full-record/WOS:001442989700001

Solid waste disposal and water pollution are the critical issues. Thus, this work aims to convert common domestic fruit wastes namely mangosteen peel (MP) and pomegranate peel (PP) into a mesoporous activated carbon (MPPP-AC) via microwave-induced strong alkaline salt (K2CO3) activation. The potential application of MPPP-AC was tested for the removal of two structurally different toxic cationic dyes namely fuchsin basic (FB) and methylene violet (MV). The physicochemical properties of MPPP-AC were analyzed utilizing several analyses such as XRD, SEM-EDX FTIR, pHpzc,and BET analysis. The adsorptive performance of MPPP-AC was optimized by using response surface methodology (RSM) with Box-Behnken design (BBD). Three key adsorption variables including the dose of MPPP-AC (A: 0.02-0.1 g/100 mL), solution pH (B: 4-10), and time of contact (C: 10-60 min) were optimized in the BBD. The highest FB removal and MV removal were found to be 80.2 % and 92.8 % respectively at 0.1 g/100 mL of MPPP-AC dosage and solution pH = 10. Thus, the best fit for the adsorption isotherm data for FB and MV dyes was the Freundlich model, whereas the pseudo-second-order model was best explained for the kinetic data. The MPPP-AC has maximum adsorption capacity for FB (85.5 mg/g) and MV (90.1 mg/g). Various forms of interaction were involved in the MV and FB dye binding process onto MPPP-AC such as the filling of pores, it-it stacking, hydrogen bonding, and electrostatic forces. The finding of this research exhibits the possibility of transforming a blending of MP and PP wastes into activated carbon which shows desirable adsorptive performance for eliminating cationic dyes from water.