Effect of Activated Palm Kernel Shell Nanoparticles as a Bio-filler on the Mechanical Properties Vulcanized Natural Rubber

Oil palm wastes, such as palm kernel shell (PKS), can be beneficially used as value-added additive for natural rubber. Converting PKS into activated palm kernel shell (APKS) and transforming into nano size APKS (n-APKS) can enhance the performance of vulcanizates natural rubber (NR). Performance of...

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书目详细资料
发表在:BioResources
主要作者: 2-s2.0-85218955147
格式: 文件
语言:English
出版: North Carolina State University 2025
在线阅读:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85218955147&doi=10.15376%2fbiores.20.2.2811-2826&partnerID=40&md5=48ade9fc46723d2e2200b9a8eafd79e0
实物特征
总结:Oil palm wastes, such as palm kernel shell (PKS), can be beneficially used as value-added additive for natural rubber. Converting PKS into activated palm kernel shell (APKS) and transforming into nano size APKS (n-APKS) can enhance the performance of vulcanizates natural rubber (NR). Performance of n-APKS incorporated NR has been evaluated with different loadings (0 to 10 phr) in several tests, such as cure characteristic, bound rubber content (BRC), swelling, tensile, and abrasion resistance index (ARI). The presence of n-APKS decreased minimum torque from 0.54 dN.m to 0.31 dN.m, indicating enhancement processability. The cure index peaked at n-APKS loading of 5 phr (F4), which indicated the effective crosslinking in NR matrix. The F4 (5 phr) formulation outperformed others, featuring a BRC of 4.08%, a crosslink density of 8.65 x 10-5 mol/cm3, a tensile strength of 19 MPa, a M300 at 3.33 MPa, a reinforcement index of 3.78%, and an ARI of 38% with relatively low elongation at break (648%). The optimum loading of 5 phr is deemed a promising bio-filler option for the rubber industry and it also helps to reduce environmental waste disposal issues. © 2025, North Carolina State University. All rights reserved.
ISSN:19302126
DOI:10.15376/biores.20.2.2811-2826